Why Fitch?

There’s nothing quite like opening the door and breathing fresh, clean, air—but how clean is the air you’re breathing right now? Unless you’re a scientist with a chemistry lab at your fingertips, there’s no real way of knowing. The gases you’re sucking up through your nose could be slowly killing you: according to the World Health Organization, around two million people die prematurely from the effects of polluted air every single year. Air pollution is a huge problem—and not just for people living in smog-choked cities: through such things as global warming and damage to the ozone layer, it has the potential to affect us all. So what exactly causes this major environmental issue and what can we do about it? Let’s take a closer look!

What is air pollution?

Air lets our living planet breathe—it’s the mixture of gases that fills the atmosphere, giving life to the plants and animals that make Earth such a vibrant place. Broadly speaking, air is almost entirely made up of two gases (78 percent nitrogen and 21 percent oxygen), with a few other gases (such as carbon dioxide and argon) present in absolutely minute quantities. We can breathe ordinary air all day long with no ill effects, so let’s use that simple fact to define air pollution, something like this:

Air pollution is a gas (or a liquid or solid dispersed through ordinary air) released in a big enough quantity to harm the health of people or other animals, kill plants or stop them growing properly, damage or disrupt some other aspect of the environment (such as making buildings crumble), or cause some other kind of nuisance (reduced visibility, perhaps, or an unpleasant odor).

As with water pollution and land contamination, it’s the quantity (or concentration) of a chemical in the air that makes the difference between “harmless” and “pollution.” Carbon dioxide (CO2), for example, is present in the air around you at a typical concentration of less than 0.05 percent and breathing it in usually does no harm (you breathe it out all day long); but air with an extremely high concentration of carbon dioxide (say, 5–10 percent) is toxic and could kill you in a matter of minutes. Since Earth’s atmosphere is very turbulent—many of us live in windy countries—air pollution will often disperse relatively quickly. In less enlightened times, factory operators thought that if they built really high smokestacks, the wind would simply blow their smoke away, diluting and dispersing it so it wouldn’t be a problem.

Top-ten gases in air pollution

Any gas could qualify as pollution if it reached a high enough concentration to do harm. Theoretically, that means there are dozens of different pollution gases. In practice, about ten different substances cause most concern:

  1. Sulfur dioxide: Coal, petroleum, and other fuels are often impure and contain sulfur as well as organic (carbon-based) compounds. When sulfur (spelled “sulphur” in some countries) burns with oxygen from the air, sulfur dioxide (SO2) is produced. Coal-fired power plantsare the world’s biggest source of sulfur-dioxide air pollution, which contributes to smog, acid rain, and health problems that include lung disease.
  2. Carbon monoxide: This highly dangerous gas forms when fuels have too little oxygen to burn completely. It spews out in car exhausts and it can also build up to dangerous levels inside your home if you have a poorly maintained gas boiler, stove, or fuel-burning appliance. (Always fit acarbon monoxide detectorif you burn fuels indoors.)
  3. Carbon dioxide: This gas is central to everyday life and isn’t normally considered a pollutant: we all produce it when we breathe out and plants such as crops and trees need to “breathe” it in to grow. However, carbon dioxide is also a greenhouse gas released by engines and power plants. Since the beginning of the Industrial Revolution, it’s been building up in Earth’s atmosphere and contributing to the problem of global warming and climate change.
  4. Nitrogen oxides: Nitrogen dioxide (NO2) and nitrogen oxide (NO) are pollutants produced as an indirect result of combustion, when nitrogen and oxygen from the air react together. Nitrogen oxide pollution comes from vehicle enginesand power plants, and plays an important role in the formation of acid rain, ozone and smog. Like carbon dioxide, nitrogen oxides are also greenhouse gases (ones that contribute to global warming).
  5. Volatile organic compounds (VOCs): These carbon-based (organic) chemicals evaporate easily at ordinary temperatures and pressures, so they readily become gases. That’s precisely why they’re used as solvents in many different household chemicals such as paints, waxes, and varnishes. Unfortunately, they’re also a form of air pollution: they’re believed to have long-term (chronic) effects on people’s health and they also play a role in the formation of ozone and smog.
  6. Particulates: These are the sooty deposits in air pollution that blacken buildings and cause breathing difficulties. Particulates of different sizes are often referred to by the letters PM followed by a number, so PM10means soot particles of less than 10 microns (10 millionths of a meter or 10µm in diameter). In cities, most particulates come from traffic fumes.
  7. Ozone: Also called trioxygen, this is a type of oxygen gas whose molecules are made from three oxygen atomsjoined together (so it has the chemical formula O3), instead of just the two atoms in conventional oxygen (O2). In the stratosphere (upper atmosphere), a band of ozone (“the ozone layer”) protects us by screening out harmful ultravioletradiation (high-energy blue light) beaming down from the Sun. At ground level, it’s a toxic pollutant that can damage health. It forms when sunlight strikes a cocktail of other pollution and is a key ingredient of smog (see box below).
  8. Chlorofluorocarbons (CFCs): Once thought to be harmless, these gases were widely used in refrigeratorsandaerosol cans until it was discovered that they damaged Earth’s ozone layer. We discuss this in more detail down below.
  9. Unburned hydrocarbons: Petroleum and other fuels are made of organic compounds based on chains of carbon and hydrogen atoms. When they burn properly, they’re completely converted into harmless carbon dioxide and water; when they burn incompletely, they can release carbon monoxide or float into the air in their unburned form, contributing to smog.
  10. Lead and heavy metals: Leadand other toxic “heavy metals” can be spread into the air either as toxic compounds or as aerosols(when solids or liquids are dispersed through gases and carried through the air by them) in such things as exhaust fumes and the fly ash (contaminated waste dust) from incinerator smokestacks.

What are the causes of air pollution?

Anything people do that involves burning things (combustion), using household or industrial chemicals (substances that cause chemical reactions and may release toxic gases in the process), or producing large amounts of dust has the potential to cause air pollution. Step back a century or two and the cause of most air pollution was easy to identify: filthy factories, powering the Industrial Revolution. Today, tighter air pollution laws, greater environmental awareness, and determined campaigns mounted by local communities make it far harder—though by no means impossible—for factories to pollute in post-industrial nations such as the United States and Britain.

Where, then, does modern air pollution come from? By far the biggest culprit today is traffic, though power plants and factories continue to make an important contribution. Before we start laying the blame for air pollution, let’s remember one very important thing: most of us drive (or travel in) cars, use electricity, and buy goods made in factories. If we’re pointing fingers, ultimately we’re going to have to point them at ourselves.

Now let’s look a bit more closely at the three key sources of air pollution.


There are something like a half billion cars on the road today—one for every two people in rich countries such as the United States. Virtually all of them are powered by gasoline and diesel engines that burn petroleum to release energy. Petroleum is made up of hydrocarbons (large molecules built from hydrogen and carbon) and, in theory, burning them fully with enough oxygen should produce nothing worse than carbon dioxide and water. In practice, fuels aren’t pure hydrocarbons and engines don’t burn them cleanly. As a result, exhausts from engines contain all kinds of pollution, notably particulates (soot of various sizes), carbon monoxide (CO, a poisonous gas), nitrogen oxides (NOx), volatile organic compounds (VOCs), and lead—and indirectly produce ozone. Mix this noxious cocktail together and energize it with sunlight and you get the sometimes brownish, sometimes blueish fog of pollution we call smog, which can hang over cities for days on end.


Smog isn’t the stuff that pumps from a car’s tailpipe or drifts from a factory smokestack—it’s the nasty brown or blue haze that builds up over a city as a result.

Smog (a combination of the words “smoke” and “fog”) forms when sunlight acts on a cocktail of pollutant gases such as nitrogen and sulfur oxides, unburned hydrocarbons, and carbon monoxide; that’s why it’s sometimes called photochemical smog (the energy in light causes the chemical reaction that makes smog). One of the most harmful constituents of smog is a toxic form of oxygen called ozone, which can cause serious breathing difficulties and even, sometimes, death. When smog is rich in ozone, it tends to be a blueish color, otherwise it’s more likely to be brown.

Although smog can happen in any busy city, it’s a particular problem in places such as Los Angeles where the local climate (influenced by the ocean and neighboring mountains) regularly causes what’s known as a temperature inversion. Normally, air gets colder the higher up you go but in a temperature inversion the opposite happens: a layer of warm air traps a layer of cold air nearer the ground. This acts like a lid over a cloud of smog and stops it from rising and drifting away. Largely because of their traffic levels, smog afflicts many of the world’s busiest cities, including Athens, Beijing, Mexico City, Milan, and Tokyo.

Chart: Most of the world’s major cities routinely exceed World Health Organization (WHO) air pollution guidelines. This chart compares annual mean PM2.5levels in 10 cities around the world with the WHO guideline value of 10μg per cubic meter (dotted line). PM2.5 particulates are those smaller than 2.5 microns and believed to be most closely linked with adverse health effects. Chart drawn using data from Ambient (outdoor) air pollution in cities database 2014 courtesy of World Health Organization.

Power plants

Renewable energy sources such as solar panels and wind turbines are helping us generate a bigger proportion of our power every year, but the overwhelming majority of electricity (around 70 percent in the United States, for example) is still produced by burning fossil fuels such as coal, gas, and oil, mostly in conventional power plants. Just like car engines, power plants should theoretically produce nothing worse than carbon dioxide and water; in practice, fuels are dirty and they don’t burn cleanly, so power plants produce a range of air pollutants, notably sulfur dioxide, nitrogen oxides, and particulates. (They also release huge amounts of carbon dioxide, a key cause of global warming and climate change when it rises and accumulates in the atmosphere. We discuss this a bit more down below.)

Industrial plants and factories

Plants that produce the goods we all rely on often release small but significant quantities of pollution into the air. Industrial plants that produce metals such as aluminum and steel, refine petroleum, produce cement, synthesize plastic, or make other chemicals are among those that can produce harmful air pollution. Most plants that pollute release small amounts of pollution continually over a long period of time, though the effects can be cumulative (gradually building up). Sometimes industrial plants release huge of amounts of air pollution accidentally in a very short space of time. One notable case happened in Bhopal, India in December 1984, when a large chemical plant run by the Union Carbide company released a poisonous gas (methyl isocyanate) that hung over the local area, killing around 3000 people and injuring thousands more. (Wikipedia’s article on the Bhopal Disaster gives a comprehensive account of what happened.)

Other causes of air pollution

Although traffic, power plants, and industrial and chemical plants produce the majority of Earth’s manmade air pollution, many other factors contribute to the problem. In some parts of the world, people still rely on burning woodfuel for their cooking and heating, and that produces indoor air pollution that can seriously harm their health (solar cookers are one solution to that problem). In some areas, garbage is incinerated instead of being recycled or landfilled and that can also produce significant air pollution unless the incinerators are properly designed to operate at a high enough temperature (even then, there is a toxic residue left behind that must be disposed of somehow).

What effects does air pollution have?

Air pollution can harm the health of people and animals, damage crops or stop them growing properly, and make our world unpleasant and unattractive in a variety of other ways.

Human health

We know air pollution is a bad thing without even thinking about it. Have you ever coughed when a truck drove past belching out its sooty exhaust? Instinctively, you cough to clear your lungs and protect your body and you might even cover your face with your handkerchief or sleeve to filter the air until it feels safe to breathe deeply again. You don’t have to be told that pollution like this might harm your health to want to steer clear of it: your body takes action automatically. The only trouble is, we can’t always see or smell air pollution, tell when it’s affecting us, or know how it might harm us days, months, or even years in the future.

Sometimes the connection between air pollution and human health is obvious, as in the Bhopal Disaster. Another notable incident happened in London, England in 1952 when thick, deadly pollution known as the Great Smog, caused by people burning coal in home fires and coal-fired power plants, killed an estimated 4000 people. Other times, it’s much more difficult to make the link. Some estimates suggest perhaps 10-20 percent of cancers are caused by air pollution of one kind or another, but cancers can take a long time to develop and many other things can cause them too. Proving a direct link with a particular kind of air pollution (say, a garbage incinerator in your community or a neighbor who persistently burns plastic on garden bonfires) is very difficult.

According to the World Health Organization (WHO), air pollution is one of the world’s biggest killers: it causes around two million people to die prematurely each year. Many of these deaths happen in developing countries (over half a million in India alone), but wealthier industrial nations suffer too: in the United States, for example, around 41,000 people a year are estimated to die early because of air pollution. Imagine how much media coverage there would be if two million people (that’s roughly the population of Houston, Texas or the West Midlands conurbation in England) were killed in a terrorist incident or an earthquake. Because air pollution kills quietly and relentlessly, and its finger is hard to detect on the trigger, people barely seem to notice—or care.

Deaths aren’t the only human consequence of air pollution. For every person who dies, hundreds or thousands more suffer breathing problems such as asthma and bronchitis. Workers exposed to high levels of dust sometimes suffer years of misery before dying from illnesses such as silicosis.

Agricultural effects

Farming is as much of an art as a science; crops can thrive—or fail—for all sorts of reasons. One of the things that characterized the 20th century was the huge growth in industrial agriculture—using fertilizers, pesticides, and so on to increase crop yields and feed the world’s ever-growing population. These aren’t the only chemicals that crops are exposed to, however. We know that air pollution (in common with water pollution) can seriously affect the growth of plants. At one end of the spectrum, it’s easy to find chemical residues (everything from toxic heavy metals such as lead to cocktails of brake fluids and other chemicals) in plants that grow alongside highways. At the opposite extreme, the huge increase in atmospheric carbon dioxide now causing global warming and climate change is expected to have a major impact on the world’s agriculture (reducing crop yields in some places but potentially increasing yields elsewhere).

Other effects

Wander the streets of a big city and you’ll notice quite quickly how dirty the buildings look, even in areas where there are no factories or power plants. Exhaust fumes from traffic are generally to blame. Apart from blackening buildings with soot, they also contribute to acid rain (see below) that can wear away stonework in a matter of years or decades.

How air pollution works on different scales

Air pollution can happen on every scale, from the local to the global. Sometimes the effects are immediate and happen very near to the thing that caused them; but they can also happen days, months, or even years later—and in other cities, countries, or continents.

How can we solve the problem of air pollution?

As we discovered in the last section, air pollution means different problems at different scales—in other words, it’s not one single problem but many different ones. Solving a problem like passive smoking (how one person’s cigarette smoke can harm other people’s health) is very different to tackling a problem like global warming, though both involve air pollution and they do have some things in common (both problems, for example, require us to think about how our behavior can affect other people in the short and long term and to act more considerately). Generally, air pollution is tackled by a mixture of technological solutions, laws and regulations, and changes in people’s behavior.

Technological solutions

It’s very easy to criticize power plants, factories, and vehicles that belch polluting gases into the atmosphere, but virtually all of us rely on these things—ultimately, we are the people polluting. Solving air pollution is also a challenge because many people have a big investment in the status quo (carrying on with the world much as it is today). For example, it’s easier for car makers to keep on making gasoline engines than to develop electric cars or ones powered by fuel cells that produce less pollution. The world has thousands of coal-fired power plants and hundreds of nuclear power stations and, again, it’s easier to keep those going than to create an entirely new power system based on solar panels, wind turbines, and other forms of renewable energy(though that is happening slowly).